To create a PRIMARY KEY constraint on the "ID" column when the table is already created, use the following SQL:
 

ALTER TABLE Persons
ADD PRIMARY KEY (ID);

To allow naming of a PRIMARY KEY constraint, and for defining a PRIMARY KEY constraint on multiple columns, use the following SQL syntax:
 
ALTER TABLE Persons
ADD CONSTRAINT PK_Person PRIMARY KEY (ID,LastName);

If you use ALTER TABLE to add a primary key, the primary key column(s) must have been declared to not contain NULL values (when the table was first created).

 



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